压杆材料对反射超压测量影响研究

用有限元方法对应变式压杆压力传感器系统进行研究,研究3种不同材料的压杆对应变式压杆压力传感器测试结果的影响;数值模拟了不同上升前沿的梯形脉冲及三角形脉冲条件下不同材料压杆的响应误差.研究结果表明,铍压杆对测试结果的影响最小,铝合金压杆影响最大;另外,脉冲上升前沿和测量位置对测试结果的影响也很大.模拟结果对压杆材料的选择有一定参考价值.     

初始压力对爆轰波在管道内传播的影响

建立爆轰管道研究不同初始压力下爆轰波在管道内传播规律.选用CH4+2O2气体,采用光纤探针测量爆轰波在管道内的传播速度,采用烟迹法记录爆轰波胞格结构.结果表明:爆轰波在管道内传播时出现5种不同传播模式,分别为稳态式、快速波动式、结巴式、驰振式与失效模式.在稳态传播模式下,爆轰波局部速度波动很小且平均速度接近理论爆轰CJ速度,并呈现多头胞格结构.随着初始压力的降低,爆轰波局部速度波动增加且其平均速度产生衰减.在驰振式爆轰解耦处,爆轰波胞格结构消失,过载爆轰时,重新形成胞格结构.进一步降低初始压力至爆轰失效时,则无胞格结构.     

硫化锌精矿加压酸浸渣回收工艺及其环境影响分析

以硫化锌精矿加压酸浸渣为研究对象,系统的分析了加压酸浸渣浮选回收硫精矿,浮选尾矿经两段浸出、氧化除铁、锌粉置换和蒸发浓缩等工序回收七水硫酸锌的工艺过程,并分析了该过程产生的废气、废水、废渣和噪声等对周围环境的影响。     

三维SHPB装置设计及原理研究

针对一维SHPB实验设备无法进行三维预应力不等值情况下的冲击实验问题,在确保中国矿业大学(北京)原有一维SHPB实验装置中动力发射系统及子弹不改变的前提下,设计了可以进行对试件进行三维施压的正方形输入杆、输出杆、吸收杆及输入杆中与子弹接触部位由圆变方的过渡杆装置,采用应力波基础理论分析和数值模拟的方法,得到了过渡杆中的应力波传播规律,研究结果表明:应力波在圆变方扩散杆中传播时,由于强度吸收现象,过渡杆越长,波幅下降的程度就越低,当长度达到500 mm时,应力波在其中的弥散现象已经很小,能够满足整个实验系统的准度要求.      

超临界乙醇制备TiO2/石墨烯纳米复合材料及其表征

以氧化石墨为载体、钛酸异丙酯为前驱体,利用超临界乙醇的超临界性能和还原性,制得了晶型完善的锐钛矿TiO2/石墨烯纳米复合材料.通过红外光谱（FTIR）、X射线光电子能谱（XPS）对采用Hummers法制得的氧化石墨（GO）进行表征;同时利用透射电子显微镜（TEM）、X射线衍射仪（XRD）对TiO2/石墨烯纳米复合材料进行研究.结果表明：成功制得了氧化石墨（GO）和晶型完善的锐钛矿TiO2/石墨烯纳米复合材料,并且发现二氧化钛在石墨烯纳米片层上呈现为有规则的颗粒,分散均匀,平均粒径为8.24 nm.     

Synthesis of Ta C and Ta_2C from tantalum and graphite in the laser-heated diamond anvil cell

The pressure dependence of the onset of the formation of Ta C and Ta2 C from the elements has been investigated by in situ X-ray diffraction and pyrometry.Ta C has been synthesized by the reaction of Ta and graphite at pressures between 8.6 and 14.3 GPa and at temperatures up to 2,300 K using a laser-heated diamond anvil cell. The products were characterized by X-ray diffraction. Ta and graphite begin to react around 1,100 K at ambient pressure conditions, and the reaction temperature increases with increasing pressure. A linear extrapolation of these data is consistent with recent observations of the formation of Ta C at 90 GPa and 3,600 K. We show that diffusion of carbon into tantalum significantly changes the lattice parameter of up to 2 % in the pressure range of up to19 GPa. In some experiments, Ta2 C was formed concomitantly. The experimentally determined bulk modulus of Ta2 C is B0;exp：= 286（5） GPa. Other tantalum carbide phases were not observed.     

Structural phase transition and metallization in compressed SrC_2

The structural, dynamical, and electronic properties of compressed Sr C2 were systematically investigated up to 200 GPa by using ab initio method. Three new phases are obtained by means of evolutionary algorithm. The confirmed most stable structure has C2/c symmetry at zero pressure, which transforms into an orthorhombic Cmcm phase at 4.5 GPa, followed by another orthorhombic Immm phase, which is stabilized at wide pressure range of 21.5–123.5 GPa, and then transformed into Mg B2-type phase（space group, P6/mmm）. Although Sr C2 has similar structural transformation to that of compressed Ca C2, Sr C2 holds small electron–phonon coupling,which leads to its low superconducting critical temperature（only 1.8 K）.     

Compression behavior of Sm）2Ti2O7-pyrochlore up to 50 GPa：single-crystal X-ray diffraction and density functional theory calculations

Single-crystal X-ray diffraction at pressures up to 50 GPa has been employed to study the compression behavior of Sm2Ti2O7-pyrochlore. In contrast to earlier reports, we observed no pressure-induced amorphization or pressure-induced anion disorder up to 50 GPa. The experimental study has been complemented by density functional theory-based calculations. A combination of the theoretical and experimental data yields a bulk modulus of 185 GPa, significantly higher than a value which had been reported earlier. In comparison to earlier work, the current study provides more reliable data due to the use of neon as a pressure medium, which provides a more hydrostatic pressure than the aluminum, which had been employed as a pressure medium in the earlier studies. An analysis of the compressibility of Al2B2O7 pyrochlores shows an approximately linear dependence of the bulk modulus on the unit cell volume.     

Microstructure and oxidation resistance of SiC–MoSi2 multi-phase coating for SiC coated C/C composites

In order to improve the anti-oxidation of C/C composites, a SiC–MoSi2multi-phase coating for SiC coated carbon/carbon composites(C/C)was prepared by low pressure chemical vapor deposition(LPCVD) using methyltrichlorosilane(MTS) as precursor, combined with slurry painting from MoSi2 powder. The phase composition and morphology were analyzed by scanning electron microscope(SEM) and X-ray diffraction(XRD) methods, and the deposition mechanism was discussed. The isothermal oxidation and thermal shock resistance were investigated in a furnace containing air environment at 1500 1C. The results show that the as-prepared SiC–MoSi2coating consists of MoSi2 particles as a dispersing phase and CVD–SiC as a continuous phase. The weight loss of the coated samples is 1.51% after oxidation at 1500 1C for 90 h, and 4.79% after 30 thermal cycles between 1500 1C and room temperature. The penetrable cracks and cavities in the coating served as the diffusion channel of oxygen, resulted in the oxidation of C/C composites, and led to the weight loss in oxidation.     

油井下用光纤温度压力传感器

研制了一种基于光纤F-P腔与光纤Bragg光栅的温度压力传感器,用于监测油井下的压力和温度。该传感器通过F-P腔腔长的变化监测油井下压力,通过光纤Bragg光栅反射波长的变化监测油井下温度。传感器测压范围0~69 MPa,实验测试和标定结果表明,传感器的压力响应与F-P腔腔长呈良好线性关系,线性拟合度为0.999 999;传感器测温范围5~175℃,温度精度±1℃。实际应用证明,该传感器可实时在线监测井下压力和温度状况,运行正常。